双单体法合成两亲性超支化聚(β-环糊)及其性能研精究般若黑反应1d合成沉降&干燥2d路线反应2h沉降&干燥2d反应4d+透析&干燥10d反应1d+沉降&干燥2dBx-OTs单体反应2d+透析&干燥10dBx-NH2单体HBPPNIPAm-COOH接枝核壳HBP合成路线DMAPHCl吡啶Bx-OTsBx-NH2HBP接枝核壳HBPLCSTLCST粒度14001200HBP1000Diam(nm)800600400200接枝核壳HBPLCST=52℃0-200102030405060708090100T(℃)CMCCMCCMC70001×10-6335nm339nm5×10-66000ExcitationIntensity(a.u.)1×10--5550005×10-440001×10-430005×10-320001×10-310005×10-21×10-205×10-11×10-15×103003203403601405070100280Wavelength(nm)I335/I339CMC5mg/ml1.14mg/ml1.03mg/ml0.92mg/ml0.81mg/ml0.70.5mg/ml0.4mg/ml0.3mg/ml0.2mg/ml0.1mg/mlCMC=0.71mg/ml-3-2-10111logC(mg/ml)光LL(X×10-5mol/L)0mg/ml-9荧600pH=7.4包合2mg/ml3mg/ml94004mg/mlemissionintensity(a.u.)5mg/ml92009000880086008400450460470440Wavelength(nm)光Wavelength=457.8nm-荧包合9400emissionintensity(a.u.)结论9200CMC：9000合物可点对以上，聚8800稳定的包合LL形成86000.00.512345Concentration(mg/ml)GPCDSC紫总结TGA外核粒磁单体改性测定度双单体法LCST红DSC外紫外客体包载荧光
